The cement was chemistry doing exactly what it must: gel colours are WATER-BASED, and water is chocolate's one unforgivable enemy - even a drop seizes it into the angry paste you met. Your gels are innocent for cakes and lethal for chocolate.
The correct system: FAT-SOLUBLE (oil-soluble) powder colours, dissolved into warmed COCOA BUTTER - not into the chocolate itself. The course ratio: roughly 10 parts cocoa butter to 1 part colour. That coloured cocoa butter is your paint - brushed, sponged or sprayed into the polished mould cavities, allowed to set, and THEN the tempered shell is cast over it. The colour transfers onto the shell surface with the mould's shine.
The cocoa butter should be at its own working temperature when painting (and yes, it tempers like chocolate does - properly handled it sets with shine and snap rather than smearing).
Buy "oil-soluble" or "chocolate-grade" powder colours specifically - the packet must say it. Everything labelled gel stays in cake country, where it belongs ๐จ